Anyone 18 years or over can be a Trustee of an SMSF as long as they are not under a legal disability (such as mental incapacity) or a disqualified person.
A person is disqualified if they:
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have been convicted of an offence involving dishonesty
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have been subject to a civil penalty order under the super laws
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are insolvent under administration (including being an undischarged bankrupt)
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have been disqualified by a court or regulator (for example, by us or APRA).
A Company can't be a Trustee if:
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a director or other responsible officer of the Company (such as a secretary or executive officer) is a disqualified person
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a receiver, official manager or provisional liquidator has been appointed to the company action has started to wind up the Company.